Formation of ordered mesoscopic polymer arrays by dewetting

被引：124

作者：

Karthaus, O ^{[1
]}

Gråsjö, L ^{[1
]}

Maruyama, N ^{[1
]}

Shimomura, M ^{[1
]}

机构：

[1] Hokkaido Univ, Res Inst Elect Sci, Sapporo, Hokkaido 0600812, Japan

来源：

CHAOS | 1999年 / 9卷 / 02期

关键词：

D O I：

10.1063/1.166407

中图分类号：

O29 [应用数学];

学科分类号：

070104 ;

摘要：

It could be shown that by a simple casting process from solution two-dimensionally ordered arrays of mesoscopic (i.e., in the range of submicrometer to micrometer) polymer aggregates on solid substrates can be formed. Patterns were investigated by optical microscopy and atomic force microscopy. The pattern formation was observed in situ by optical and fluorescence microscopy and it was found that a "fingering instability'' at the three-phase-line of a solution droplet is the crucial process for pattern formation. (C) 1999 American Institute of Physics. [S1054-1500(99)00902-7].

引用

页码：308 / 314

页数：7

共 34 条

[1] WETTING AND SLIPPAGE OF POLYMER MELTS ON SEMI-IDEAL SURFACES [J].

BROCHARDWYART, F ;

DEGENNES, PG ;

HERVERT, H ;

REDON, C .

LANGMUIR, 1994, 10 (05) :1566-1572

[2] THE THICKNESS OF SURFACE-TENSION-GRADIENT-DRIVEN SPREADING FILMS [J].

CARLES, P ;

CAZABAT, AM .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1993, 157 (01) :196-201

[3] FINGERING INSTABILITY OF THIN SPREADING FILMS DRIVEN BY TEMPERATURE-GRADIENTS [J].

CAZABAT, AM ;

HESLOT, F ;

TROIAN, SM ;

CARLES, P .

NATURE, 1990, 346 (6287) :824-826

[4]

CAZABAT AM, 1994, LECT NOTES SUMM SCH

[5] WETTING - STATICS AND DYNAMICS [J].

DEGENNES, PG .

REVIEWS OF MODERN PHYSICS, 1985, 57 (03) :827-863

[6] Nonlinear dynamics and breakup of free-surface flows [J].

Eggers, J .

REVIEWS OF MODERN PHYSICS, 1997, 69 (03) :865-929

[7] Unstable polymer bilayers .1. Morphology of dewetting [J].

Faldi, A ;

Composto, RJ ;

Winey, KI .

LANGMUIR, 1995, 11 (12) :4855-4861

[8] Spreading and instabilities induced by a solutal Marangoni effect [J].

Fanton, X ;

Cazabat, AM .

LANGMUIR, 1998, 14 (09) :2554-2561

[9] Thickness and shape of films driven by a Marangoni flow [J].

Fanton, X ;

Cazabat, AM ;

Quere, D .

LANGMUIR, 1996, 12 (24) :5875-5880

[10] Control of polystyrene film dewetting through sulfonation and metal complexation [J].

Feng, Y ;

Karim, A ;

Weiss, RA ;

Douglas, JF ;

Han, CC .

MACROMOLECULES, 1998, 31 (02) :484-493

← 1 2 3 4 →