One-dimensional (1D) helical and 2D homochiral metal-organic frameworks built from a new chiral octahydrobinaphthalene-derived dicarboxylic acid

被引：22

作者：

Ouyang, Xiang ^{[1
]}

Chen, Zhenxia ^{[1
]}

Liu, Xiaofeng ^{[1
]}

Yang, Yongtai ^{[1
]}

Deng, Mingli ^{[1
]}

Weng, Linhong ^{[1
]}

Zhou, Yaming ^{[1
]}

Jia, Yu ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 09期

关键词：

chiral ligand; helical; homochiral metal-organic frameworks; solvothermal reaction;

D O I：

10.1016/j.inoche.2008.04.023

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three homochiral metal-organic frameworks (MOFs) based on enantiopure chiral ligand: (R)-2,2'-dimethoxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-3,3'-dicarboxylic acid (HA), namely Cd(L)(Py)(3) 1, Cu(L)(Py)(3) 2, Na[Cd(L)(LH)]center dot 2.5H(2)O 3(Py= pyridine), were firstly synthesized, under solvothermal reactions. X-ray single-crystal diffraction studies reveal that 1 and 2 adopt one-dimensional (1 D) infinite helical structures, while 3 possesses 2D chiral framework structure adopting ABAB offset stacking modes along the a-axis. Thermogravimetric analyses (TGA) display that 3 is thermally stable to 330 C which is rare for homochiral MOB. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：948 / 950

页数：3

共 20 条

[1] HOST-GUEST COMPLEXATION .8. MACROCYCLIC POLYETHERS SHAPED BY 2 RIGID SUBSTITUTED DINAPHTHYL OR DITETRALYL UNITS [J].

CRAM, DJ ;

HELGESON, RC ;

PEACOCK, SC ;

KAPLAN, LJ ;

DOMEIER, LA ;

MOREAU, P ;

KOGA, K ;

MAYER, JM ;

CHAO, Y ;

SIEGEL, MG ;

HOFFMAN, DH ;

SOGAH, GDY .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (10) :1930-1946

[2]

Cui Y, 2002, ANGEW CHEM INT EDIT, V41, P1159, DOI 10.1002/1521-3773(20020402)41:7<1159::AID-ANIE1159>3.0.CO

[3]

2-5

[4] Hydrogen storage in a microporous metal-organic framework with exposed Mn2+ coordination sites [J].

Dinca, Mircea ;

Dailly, Anne ;

Liu, Yun ;

Brown, Craig M. ;

Neumann, Dan. A. ;

Long, Jeffrey R. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) :16876-16883

[5] Homochiral metal-organic frameworks based on transition metal bisphosphonates [J].

Evans, OR ;

Manke, DR ;

Lin, WB .

CHEMISTRY OF MATERIALS, 2002, 14 (09) :3866-3874

[6] Chiral porous solids based on lamellar lanthanide phosphonates [J].

Evans, OR ;

Ngo, HL ;

Lin, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (42) :10395-10396

[7] Synthesis and hydrogen sorption properties of carborane based metal-organic framework materials [J].

Farha, Omar K. ;

Spokoyny, Alexander M. ;

Mulfort, Karen L. ;

Hawthorne, M. Frederick ;

Mirkin, Chad A. ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (42) :12680-+

[8] PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE [J].

FUJITA, M ;

KWON, YJ ;

WASHIZU, S ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) :1151-1152

[9] Metal-organic frameworks as efficient materials for drug delivery [J].

Horcajada, Patricia ;

Serre, Christian ;

Vallet-Regi, Maria ;

Sebban, Muriel ;

Taulelle, Francis ;

Ferey, Gerard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (36) :5974-5978

[10] Chiral porous hybrid solids for practical heterogeneous asymmetric hydrogenation of aromatic ketones [J].

Hu, AG ;

Ngo, HL ;

Lin, WB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (38) :11490-11491

← 1 2 →