Hydrosilylation of olefins and dehydrogenative double silylation of conjugated dienes catalyzed by lanthanide-imine complexes

被引：33

作者：

Takaki, K ^{[1
]}

Sonoda, K ^{[1
]}

Kousaka, T ^{[1
]}

Koshoji, G ^{[1
]}

Shishido, T ^{[1
]}

Takehira, K ^{[1
]}

机构：

[1] Hiroshima Univ, Grad Sch Engn, Dept Chem & Chem Engn, Higashihiroshima 7398527, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 52期

关键词：

hydrosilylation; double silylation; lanthanide catalyst; olefins; conjugated dienes;

D O I：

10.1016/S0040-4039(01)02027-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Divalent lanthanide-imine complexes and a related species catalyzed the hydrosilylation of olefins with phenyl- and diphenylsilane. On the other hand, conjugated dienes were converted to 1,4-bissilyl-2-butenes and 3-silacyclopentenes, accompanied with hydrogen evolution, Under similar conditions. (C) 2001 Elsevier Science Ltd. ALI rights reserved.

引用

页码：9211 / 9214

页数：4

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