Convenient preparation of a cyclopropanation reagent: alpha-siloxymethyliron complex

被引:8
作者
Du, H [1 ]
Yang, FK [1 ]
Hossain, MM [1 ]
机构
[1] UNIV WISCONSIN,DEPT CHEM,MILWAUKEE,WI 53201
关键词
D O I
10.1080/00397919608003498
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A convenient preparation of alpha-siloxymethyliron complex (7) was developed from commercially available s-trioxane and/or paraformaldehyde. For synthetic utility, iron methylidene complex (8) was generated in situ from the alpha-siloxymethyliron complex (7) and cyclopropanes (10) by treatment with alkenes.
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页码:1371 / 1377
页数:7
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