Convenient preparation of a cyclopropanation reagent: alpha-siloxymethyliron complex

被引：8

作者：

Du, H ^{[1
]}

Yang, FK ^{[1
]}

Hossain, MM ^{[1
]}

机构：

[1] UNIV WISCONSIN,DEPT CHEM,MILWAUKEE,WI 53201

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 07期

关键词：

D O I：

10.1080/00397919608003498

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient preparation of alpha-siloxymethyliron complex (7) was developed from commercially available s-trioxane and/or paraformaldehyde. For synthetic utility, iron methylidene complex (8) was generated in situ from the alpha-siloxymethyliron complex (7) and cyclopropanes (10) by treatment with alkenes.

引用

页码：1371 / 1377

页数：7

共 9 条

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