Synthesis and structure of tris[N,N-diethyl N'-diphenoxythiophosphoryl thioureato copper(I)], {Cu-I[C6H5O)(2)P(S)NC(S)N(C2H5)(2)]}(3) - An aggregate containing a [Cu3S6] nucleus

被引：22

作者：

Herrmann, E

Richter, R

Chau, NTT

机构：

[1] UNIV LEIPZIG, INST ANORGAN CHEM, D-7010 LEIPZIG, GERMANY

[2] TECH UNIV, INST ALLGEMEINE CHEM, HANOI, VIETNAM

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1997年 / 623卷 / 03期

关键词：

polynuclear Cu-I chelates; N-thiophosphoryl thiourea complexes; polyion aggregate; NMR investigation; X-ray structure;

D O I：

10.1002/zaac.19976230164

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A reduction of copper(II) to copper (I) occurs in the reaction of N,N-diethyl-N'-diphenooxythiophosphoryl thiourea (C6H5O)(2)P(S)-NH-C(S)-N(C2H5) with Cu2+ in presence of ethanol, and the trinuclear, neutral, diamagnetic chelate complex {Cu-I[(C6H5O)(2)P(S)NC(S)N(C2H5)(2)]}(3) is yielded in form of colourless othorhombic crystals (a = 18.588 Angstrom, b = 25.875 Angstrom, c = 24.881 Angstrom). the lipophilically wrapped polyion aggregate contains a [Cu3S6] nucleus with trigonal planar coordinated copper(I).

引用

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页码：403 / 408

页数：6

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