Concave reagents .16. Concave reagents .17. Steric effects on the acidity of concave sulfinic acids and concave benzoic acids

被引：11

作者：

Luning, U

Baumgartner, H

Wangnick, C

机构：

[1] Institut für Organische Chemie, Chrstn.-Albrechts-Univ. zu Kiel, D-24098 Kiel

来源：

TETRAHEDRON | 1996年 / 52卷 / 02期

关键词：

D O I：

10.1016/0040-4020(95)00908-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bimacrocyclic and acyclic m-terphenylsulfinic acids 5, 7 and 9 have been synthesized. Acidities have been measured in 2-methoxyethanol/water (80:20 w/w) and have been compared to the acidities of analogous benzoic acids. Tetra-ortho-substitution of the outer aryl rings of a m-terphenyl-2'-acid leads to a decrease in acidity which is probably caused by hindered solvation of the corresponding anions.

引用

页码：599 / 604

页数：6

共 18 条

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[2]

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