Enantioselective synthesis of 2-(2-hydroxyethyl)allylsilanes from chiral beta-hydroxyesters

被引：9

作者：

Bardot, V ^{[1
]}

GelasMialhe, Y ^{[1
]}

Gramain, JC ^{[1
]}

Remuson, R ^{[1
]}

机构：

[1] UNIV CLERMONT FERRAND,URA CNRS 485,LAB CHIM SUBST NAT,F-63177 CLERMONT FERRAN,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1997年 / 8卷 / 07期

关键词：

D O I：

10.1016/S0957-4166(97)00079-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of chiral (2-substituted-2-hydroxyethyl)allylsilanes by cerium mediated trimethylsilylmethylmagnesium chloride addition on chiral beta-hydroxyesters is described. (C) 1997 Elsevier Science Ltd.

引用

页码：1111 / 1114

页数：4

共 25 条

[1] Microbial synthesis of (+)-(3R)-ethyl 3-hydroxy-3-(3,4-dimethoxyphenyl)propionate
Bardot, V
Besse, P
GelasMiahle, Y
Remuson, R
Veschambre, H
[J]. TETRAHEDRON-ASYMMETRY, 1996, 7 (04) : 1077 - 1088
[2] Bardot V, 1996, SYNLETT, P37
[3] NEW FINDINGS ON THE REGIOCHEMISTRY OF THE SILYLCUPRATION OF ALLENE
BLANCO, FJ
CUADRADO, P
GONZALEZ, AM
PULIDO, FJ
FLEMING, I
[J]. TETRAHEDRON LETTERS, 1994, 35 (47) : 8881 - 8882
[4] Bunnelle W. H., 1990, ORG SYNTH, V69, P89
[5] CHAN TH, 1979, SYNTHESIS-STUTTGART, P761
[6] ASYMMETRIC-SYNTHESIS OF BOTH ENANTIOMERS OF FLUOXETINE VIA MICROBIOLOGICAL REDUCTION OF ETHYL BENZOYLACETATE
CHENEVERT, R
FORTIER, G
RHLID, RB
[J]. TETRAHEDRON, 1992, 48 (33) : 6769 - 6776
[7] Colvin E. W., 1981, SILICON ORGANIC SYNT, P97
[8] ALPHA-METHOXY-ALPHA-TRIFLUOROMETHYLPHENYLACETIC ACID, A VERSATILE REAGENT FOR DETERMINATION OF ENANTIOMERIC COMPOSITION OF ALCOHOLS AND AMINES
DALE, JA
DULL, DL
MOSHER, HS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1969, 34 (09) : 2543 - &
[9] DIEZ A, 1992, HETEROCYCLES, V34, P13
[10] Fleming I., 1989, ORG REACTIONS, V37, P57

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