Synthesis of disubstituted cucurbit[6]uril and its rotaxane derivative

被引：149

作者：

Isobe, H ^{[1
]}

Sato, S ^{[1
]}

Nakamura, E ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 08期

关键词：

D O I：

10.1021/ol025749o

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHIC] Synthesis of diphenyl cucurbit[6]uril (CB[6]) has been achieved via co-oligomerization of diphenyl glycoluril and unsubstituted glycoluril. The unsymmetrically substituted CB[6], Ph2CB[6], was further converted to a rotaxane incorporating bis(dinitrophenyl)spermine.

引用

页码：1287 / 1289

页数：3

共 22 条

[1]

[Anonymous], ACC CHEM RES

[2]

Behrend R, 1905, LIEBIGS ANN CHEM, V339, P1

[3] MECHANISTIC STUDIES IN THE CHEMISTRY OF UREA .4. REACTIONS OF UREA, 1-METHYLUREA, AND 1,3-DIMETHYLUREA WITH BENZIL IN ACID-SOLUTION [J].

BUTLER, AR ;

LEITCH, E .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1980, (01) :103-105

[4]

Day AI, 2002, ANGEW CHEM INT EDIT, V41, P275, DOI 10.1002/1521-3773(20020118)41:2<275::AID-ANIE275>3.0.CO

[5]

2-M

[6] DECAMETHYLCUCURBIT[5]URIL [J].

FLINN, A ;

HOUGH, GC ;

STODDART, JF ;

WILLIAMS, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (11) :1475-1477

[7] CUCURBITURIL [J].

FREEMAN, WA ;

MOCK, WL ;

SHIH, NY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (24) :7367-7368

[8]

Isobe H, 2001, ANGEW CHEM INT EDIT, V40, P3364, DOI 10.1002/1521-3773(20010917)40:18<3364::AID-ANIE3364>3.0.CO

[9]

2-S

[10]

Isobe H, 2001, CHEM LETT, P1214

← 1 2 3 →