A large enhancement in the binding affinity of artificial hosts by OsVI chelation

被引：15

作者：

Jeong, KS ^{[1
]}

Lee, JW ^{[1
]}

Park, TY ^{[1
]}

Chang, SY ^{[1
]}

机构：

[1] Yonsei Univ, Dept Chem, Seoul 120749, South Korea

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 20期

关键词：

D O I：

10.1039/a906252a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mononuclear Os-VI-chelated macrocycles, self-assembled from OsO4, 2,3-dimethylbut-2-ene and bispyridyl ligands, bind diamides much more strongly than the Os-VI-free ligands (Delta Delta G = -14.6 kJ mol(-1)).

引用

页码：2069 / 2070

页数：2

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