Palladium-switchable bisnucleophiles

被引:16
作者
Castano, AM [1 ]
Ruano, M [1 ]
Echavarren, AM [1 ]
机构
[1] UNIV AUTONOMA MADRID,DEPT QUIM ORGAN,MADRID 28049,SPAIN
关键词
D O I
10.1016/0040-4039(96)01407-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The selective activation of substrates I, potential bisnucleophiles, was achieved by using different palladium catalysts. The synthetic potential of this strategy has been demonstrated in the regiodivergent synthesis of carbocycles using vinyl epoxides as the electrophiles in the palladium-catalyzed reaction with I. Copyright (C) 1996 Elsevier Science Ltd
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页码:6591 / 6594
页数:4
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