Novel cyclic hexanuclear complexes containing quadruply bonded units joined by μ6-carbonate ions

被引：33

作者：

Suen, MC

Tseng, GW

Chen, JD ^{[1
]}

Keng, TC

Wang, JC

机构：

[1] Chung Yuan Christian Univ, Dept Chem, Chungli 32023, Taiwan

[2] Soochow Univ, Dept Chem, Taipei, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 13期

关键词：

D O I：

10.1039/a903410b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three complexes {[trans-Mo-2(O2CCF3)(2)(mu-dppa)](3)(mu(6)-CO3)(mu(2)-X)(3)}F [X = Cl, Br or I; dppa = N,N-bis(diphenylphosphino)amine], are reported, which are the first cyclic, hexanuclear complexes containing quadruply bonded units joined by carbonate ions.

引用

收藏

页码：1185 / 1186

页数：2

相关论文

共 18 条

[1] SYNTHESIS, STRUCTURE, AND P-31 NMR-SPECTRA OF MO2W2CL8(PR3)4 RECTANGULAR CLUSTERS [J].

CARLIN, RT ;

MCCARLEY, RE .

INORGANIC CHEMISTRY, 1989, 28 (18) :3432-3436

[2] METAL METAL MULTIPLE BONDS IN ORDERED ASSEMBLIES .1. TETRANUCLEAR MOLYBDENUM AND TUNGSTEN CARBOXYLATES INVOLVING COVALENTLY LINKED M-M QUADRUPLE BONDS - MOLECULAR-MODELS FOR SUBUNITS OF ONE-DIMENSIONAL STIFF-CHAIN POLYMERS [J].

CAYTON, RH ;

CHISHOLM, MH ;

HUFFMAN, JC ;

LOBKOVSKY, EB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (23) :8709-8724

[3] [2 + 2] CYCLOADDITION OF RE-RE QUADRUPLE BONDS - STRUCTURAL CHARACTERIZATION OF THE 1ST CYCLOTETRARHENIUM DIYNES, (N-BU4N)2RE4CL8(MU-O)2(MU-OME)(MU-X) (X = CL OR OME) [J].

CHEN, JD ;

COTTON, FA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (15) :5857-5859

[4]

Cotton F.A., 1993, MULTIPLE BONDS METAL

[5] A NEW CYCLOTETRAMOLYBDENUM DIYNE, MO4CL8[P(OCH3)3]4 [J].

COTTON, FA ;

POWELL, GL .

INORGANIC CHEMISTRY, 1983, 22 (06) :871-873

[6] Compounds with linear, bonded trichromium chains [J].

Cotton, FA ;

Daniels, LM ;

Murillo, CA ;

Pascual, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (42) :10223-10224

[7] Tetranuclear complexes containing quadruply bonded dimolybdenum units joined by μ-hydride ions [J].

Cotton, FA ;

Daniels, LM ;

Jordan, GT ;

Lin, C ;

Murillo, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (14) :3398-3401

[8] STRUCTURAL CHARACTERIZATION OF THE 1ST CYCLOTETRAMOLYBDENUM DIYNES WITH BIDENTATE PHOSPHINES, MO4CL4(MU-CL)2(MU-OME)2(MU-DPPM)2 AND MO4CL4(MU(4)-O)(MU-CL)3(MU-OME)3(MU-DMPM)2 [J].

COTTON, FA ;

HONG, B ;

SHANG, MY .

INORGANIC CHEMISTRY, 1993, 32 (22) :4876-4881

[9]

COTTON FA, 1988, ADV INORG CHEM, P481

[10]

COTTON FA, 1991, J CLUST SCI, V2, P121