Highly propylene-selective supported zeolite-imidazolate framework (ZIF-8) membranes synthesized by rapid microwave-assisted seeding and secondary growth

被引:192
作者
Kwon, Hyuk Taek [1 ]
Jeong, Hae-Kwon [1 ,2 ]
机构
[1] Texas A&M Univ, Artie McFerrin Dept Chem Engn, College Stn, TX 77840 USA
[2] Texas A&M Univ, Mat Sci & Engn Program, College Stn, TX USA
基金
美国国家科学基金会;
关键词
MOLECULAR-SIEVE MEMBRANE; METAL-ORGANIC FRAMEWORKS; HYDROGEN SELECTIVITY; SEPARATION; MIXTURES; FILMS;
D O I
10.1039/c3cc41039k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Here we report a rapid and simple microwave-assisted seeding technique for the synthesis of high-quality ZIF-8 membranes with an average propylene-propane selectivity of about 40. The new seeding method was found to be applicable to other ZIFs including ZIF-7 and SIM-1.
引用
收藏
页码:3854 / 3856
页数:3
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