How efficient is cloud droplet formation of organic aerosols?

被引:42
作者
Lohmann, U [1 ]
Broekhuizen, K
Leaitch, R
Shantz, N
Abbatt, J
机构
[1] Dalhousie Univ, Dept Phys & Atmospher Sci, Halifax, NS B3H 3J5, Canada
[2] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
[3] Meteorol Serv Canada, Downsview, ON, Canada
[4] York Univ, Toronto, ON M3J 1P3, Canada
关键词
D O I
10.1029/2003GL018999
中图分类号
P [天文学、地球科学];
学科分类号
07 ;
摘要
Based on laboratory findings that small amounts of a soluble aerosol, such as ammonium sulfate ( AS), drastically decrease the activation diameter of moderately soluble organic aerosols, we performed studies with an adiabatic parcel model for cloud droplet nucleation. Moderately soluble organics, such as adipic acid ( AA), which represents a class of partially soluble aerosols as found in atmospheric aerosols, require a larger supersaturation and result in fewer cloud droplets as compared to pure AS and vice versa when compared to a completely insoluble species such as dust. Adding only 10% AS to AA dramatically increases its ability to become activated resulting in 36 - 92% of the cloud droplets that would be obtained from pure AS, whereas the droplet concentration in the almost pure AA aerosol is only 11 - 47% of that of AS. Addition of a surface active species, such as nonanoic acid, instead of AS to AA reduces its activated fraction by 3 - 34% as compared to the AA/AS system.
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