Spatially resolved NMR in polymer science

被引:19
作者
Blümich, B [1 ]
Blümler, P
Gasper, L
Guthausen, A
Göbbels, V
Laukemper-Ostendorf, S
Unseld, K
Zimmer, G
机构
[1] Rhein Westfal TH Aachen, Magnet Resonance Ctr, D-52056 Aachen, Germany
[2] Dunlop AG, D-63450 Hanau, Germany
关键词
D O I
10.1002/masy.19991410109
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Selected applications of spatially resolved NMR are presented, which demonstrate the use of the method for investigating applied topics relevant to polymer and materials science. Examples are given for imaging of rigid, soft, and fluid matter. They include characterization and interpretation of electrical aging in poly(ethylene), cross-link density at the interface of covulcanized elastomer sheets, and cross-filtration in hollow-fiber filler modules. A novel NMR dectector, the NMR-MOUSE, has been developed for process and quality control by relaxation measurements. Its use for non-destructive determination of the glass-transition temperature by room temperature measurements on elastomer samples is demonstrated.
引用
收藏
页码:83 / 93
页数:11
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