Polymer-stabilized gold nanoparticles with high grafting densities

被引:252
作者
Corbierre, MK [1 ]
Cameron, NS [1 ]
Lennox, RB [1 ]
机构
[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada
关键词
D O I
10.1021/la0355702
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of polymer-coated Au nanoparticles have been prepared using the "grafting-to" approach. Thiol-terminated polystyrene and poly(ethylene oxide) ligands are found to form dense brushes on the faceted gold nanoparticle surfaces. Depending on the polymer, the ligand grafting densities on the gold nanoparticles are 1.2- to 23.5-fold greater than those available via self-assembled monolayer formation of the corresponding two-dimensional gold surfaces.
引用
收藏
页码:2867 / 2873
页数:7
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共 40 条
  • [1] Visible region polarization spectroscopic studies of template-synthesized gold nanoparticles oriented in polyethylene
    Al-Rawashdeh, NAF
    Sandrock, ML
    Seugling, CJ
    Foss, CA
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (02) : 361 - 371
  • [2] FORMATION OF MONOLAYER FILMS BY THE SPONTANEOUS ASSEMBLY OF ORGANIC THIOLS FROM SOLUTION ONTO GOLD
    BAIN, CD
    TROUGHTON, EB
    TAO, YT
    EVALL, J
    WHITESIDES, GM
    NUZZO, RG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) : 321 - 335
  • [3] Nanocomposite materials for optical applications
    Beecroft, LL
    Ober, CK
    [J]. CHEMISTRY OF MATERIALS, 1997, 9 (06) : 1302 - 1317
  • [4] Brandrup J., 1999, Polymer handbook, VII
  • [5] SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM
    BRUST, M
    WALKER, M
    BETHELL, D
    SCHIFFRIN, DJ
    WHYMAN, R
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) : 801 - 802
  • [6] SYNTHESIS AND REACTIONS OF FUNCTIONALIZED GOLD NANOPARTICLES
    BRUST, M
    FINK, J
    BETHELL, D
    SCHIFFRIN, DJ
    KIELY, C
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (16) : 1655 - 1656
  • [7] Polymer-stabilized gold nanoparticles and their incorporation into polymer matrices
    Corbierre, MK
    Cameron, NS
    Sutton, M
    Mochrie, SGJ
    Lurio, LB
    Rühm, A
    Lennox, RB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (42) : 10411 - 10412
  • [8] BRUSH ADSORPTION FROM POLYDISPERSE SOLUTIONS
    DAN, N
    [J]. MACROMOLECULES, 1994, 27 (08) : 2310 - 2312
  • [9] CONFORMATIONS OF POLYMERS ATTACHED TO AN INTERFACE
    DEGENNES, PG
    [J]. MACROMOLECULES, 1980, 13 (05) : 1069 - 1075
  • [10] Fabrication and characterization of self-assembled spherical gold ultramicroelectrodes
    Demaille, C
    Brust, M
    Tsionsky, M
    Bard, AJ
    [J]. ANALYTICAL CHEMISTRY, 1997, 69 (13) : 2323 - 2328