Catalytic hydroxylation of benzene over transition-metal substituted hexagonal mesoporous silicas

被引：145

作者：

Zhang, WZ

Wang, JL

Tanev, PT

Pinnavaia, TJ

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

[2] MICHIGAN STATE UNIV,CTR FUNDAMENTAL MAT RES,E LANSING,MI 48824

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 08期

关键词：

D O I：

10.1039/cc9960000979

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ti-, V-, Cr-, Mo-, and Mn-substituted hexagonal mesoporous silicas prepared at ambient temperature by electrostatic (S+ X(-)I(+)) and neutral (S-0 I-0) surfactant templating pathways are catalytically active for the peroxide hydroxylation of benzene to phenol in the absence of a solvent.

引用

页码：979 / 980

页数：2

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