Selective alkane transformations via radicals and radical cations: Insights into the activation step from experiment and theory

被引：335

作者：

Fokin, AA

Schreiner, PR

机构：

[1] Kiev Polytech Inst, Dept Organ Chem, UA-03056 Kiev, Ukraine

[2] Univ Georgia, Dept Chem, Athens, GA 30602 USA

来源：

CHEMICAL REVIEWS | 2002年 / 102卷 / 05期

关键词：

D O I：

10.1021/cr000453m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review covers radical as well as single-electron-transfer chemistry. The structures of σ-radical cations generated from different sources are described, including the reactions of SET-oxidizers of low electrophilicity. The very fruitful combination of experiment and theory in elucidating this subject is emphasized.

引用

收藏

页码：1551 / 1593

页数：43

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