Infrared photodissociation spectroscopy of small Fe+-(CO2)n and Fe+-(CO2)n Ar clusters

被引：55

作者：

Gregoire, G ^{[1
]}

Velasquez, J ^{[1
]}

Duncan, MA ^{[1
]}

机构：

[1] Univ Georgia, Dept Chem, Athens, GA 30602 USA

来源：

CHEMICAL PHYSICS LETTERS | 2001年 / 349卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(01)01247-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Infrared photodissociation spectra of mass-selected Fe+-(CO2)(n) and Fe+-(CO2)(n)Ar clusters are reported. Under low power conditions, Fe+-(CO2)(n) clusters evaporate one CO2 molecule, while at higher fluence multiphoton absorption sorption leads to the loss of multiple ligands. Photo dissociation spectra show a blue-shift of the CO2 asymmetric stretch within the complexes which decreases with cluster size. Fe+-(CO2)(n)Ar clusters fragment by the loss of argon. Their spectra appear at the same frequencies as those for the corresponding pure Fe+-(CO2)(n) clusters, but with significantly narrower linewidths. The IR bands observed suggest specific structures for each of these complexes. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：451 / 457

页数：7

共 34 条

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