Flavonoid glycosides in bergamot juice (Citrus bergamia risso)

被引:124
作者
Gattuso, Giuseppe [1 ]
Caristi, Corrado [1 ]
Gargiulli, Claudia [1 ]
Bellocco, Ersilia [1 ]
Toscano, Giovanni [1 ]
Leuzzi, Ugo [1 ]
机构
[1] Univ Messina, Dipartimento Chim Organ & Biol, I-98166 Messina, Italy
关键词
Citrus bergamia; flavonoids; C-glucosides; O-glycosides; HPLC-DAD-ESI-MS-MS;
D O I
10.1021/jf060348z
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
A comprehensive profile of flavonoids in bergamot juice was obtained by a single DAD-ESI-LC-MSMS course. Eight flavonoids were found for the first time, five of these are C-glucosides (lucenin-2, stellarin-2, isovitexin, scoparin, and orientin 4'-methyl ether), and three are O-glycosides (rhoifolin 4'-O-glucoside, chrysoeriol 7-O-neohesperidoside-4'-O-glucoside, and chrysoeriol 7-O-neohesperidoside). A method is proposed to differentiate chrysoeriol and diosmetin derivatives, which are often indistinguishable by LC-MS-MS. In-depth knowledge of the flavonoid content is the starting point for bergamot juice exploitation in food industry applications.
引用
收藏
页码:3929 / 3935
页数:7
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