Representation of parity violating potentials in molecular main chiral axes

被引：53

作者：

Bakasov, A ^{[1
]}

Quack, M ^{[1
]}

机构：

[1] ETH Zentrum, Chem Phys Lab, CH-8092 Zurich, Switzerland

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 303卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(99)00238-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We outline an approach to electroweak quantum chemistry, which leads to an increase of E-pv by more than order of magnitude (at the CIS-RHF level), compared to established Hartree-Fock approaches. A unique axis system of molecular main chiral axes can be derived by transformation of the tensor parallel to E(pv)(ij)parallel to to diagonal form. In this form the dependence of E-pv on nuclear charge is E-pv proportional to Z(4.2 +/- 0.3) for H2O2 and H2S2 without ambiguity arising from the molecular axis system. We discuss the relation to the evolution of homochirality, spectroscopic measurements of Delta E-pv and the fundamental constants in the standard model. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：547 / 557

页数：11

共 39 条

[1] Ab initio calculation of molecular energies including parity violating interactions [J].

Bakasov, A ;

Ha, TK ;

Quack, M .

JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (17) :7263-7285

[2]

BAKASOV A, 1996, P 4 TRIEST C 1995 CH, P287

[3]

BAKASOV A, IN PRESS

[4]

BAKASOV A, 1997, CHIMIA, V7, P559

[5] PARITY NONCONSERVATION AND NMR OBSERVABLES - CALCULATION OF TL RESONANCE FREQUENCY DIFFERENCES IN ENANTIOMERS [J].

BARRA, AL ;

ROBERT, JB ;

WIESENFELD, L .

PHYSICS LETTERS A, 1986, 115 (09) :443-447

[6] THEORY OF SPIN-ORBIT COUPLING IN ATOMS .1. DERIVATION OF SPIN-ORBIT COUPLING CONSTANT [J].

BLUME, M ;

WATSON, RE .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1962, 270 (1340) :127-&

[7] THEORY OF SPIN-ORBIT COUPLING IN ATOMS .2. COMPARISON OF THEORY WITH EXPERIMENT [J].

BLUME, M ;

WATSON, RE .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1963, 271 (1344) :565-+

[8] PARITY VIOLATION INDUCED BY WEAK NEUTRAL CURRENTS IN ATOMIC PHYSICS .1. [J].

BOUCHIAT, MA ;

BOUCHIAT, C .

JOURNAL DE PHYSIQUE, 1974, 35 (12) :899-927

[9] PARITY VIOLATION INDUCED BY WEAK NEUTRAL CURRENTS IN ATOMIC PHYSICS .2. [J].

BOUCHIAT, MA ;

BOUCHIAT, C .

JOURNAL DE PHYSIQUE, 1975, 36 (06) :493-509

[10]

COMMINS ED, 1983, WEAK INTERACTIONS LE

← 1 2 3 4 →