Two novel compartmental macrocyclic dinuclear copper(II) complexes with μ2-Cl and μ2-OAc bridges

被引：13

作者：

Chu, Zhaolian ^{[1
]}

Huang, Wei ^{[1
]}

机构：

[1] Nanjing Univ, Nanjing Natl Lab Microstruct, State Key Lab Coordinat Chem, Coordinat Chem Inst,Sch Chem & Chem Engn, Nanjing 210093, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 10期

基金：

中国国家自然科学基金;

关键词：

Dinuclear copper(II) complex; Macrocyclic compounds; Schiff base; Structural elucidation;

D O I：

10.1016/j.inoche.2008.06.016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel compartmental macrocyclic dinuclear copper(II) complexes with different bridging ligands, formulated as [Cu-2(II)(L)(mu(2)-Cl] . 1.5(H2O) (1) and [Cu-2(II)(L)(mu(2)-OAc)] . (DMF) (2), are characterized by X-ray single-crystal diffraction where LH3 is a pentaclentate ligand obtained from the Schiff base condensation between 3,5-di-tert-butyl-2-hydroxybenzaldehyde and 2,6-bis(aminomethyl)-4-chlorophenol in a molar ratio of 2:1. Due to the use of different bridges and bulky t-bu groups, different molecular conformation and dimeric packing structures are observed. (C) 2008 Elsevier B.V. All rights reserved.

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页码：1166 / 1169

页数：4

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