Synthesis, ion exchange and electrochemical properties of lamellar phyllomanganates of the birnessite group

被引：96

作者：

LeGoff, P

Baffier, N

Bach, S

PereiraRamos, JP

机构：

[1] CNRS, F-94320 THIAIS, FRANCE

[2] ENSCP, CNRS, URA 1466, F-75231 PARIS, FRANCE

来源：

MATERIALS RESEARCH BULLETIN | 1996年 / 31卷 / 01期

关键词：

D O I：

10.1016/0025-5408(95)00170-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Synthesis of various X-birnessites was performed using the ion exchange properties of the sodium birnessite Na0.32MnO2,yH(2)O. Their structural and electrochemical characteristics are investigated and discussed in comparison with previous data obtained for some compounds and in relation with mechanism invoked for Li electrochemical insertion into sol-gel and chemical birnessites. Two main groups of materials are obtained with a monoclinic or hexagonal structure depending on the kind of inserted cation.

引用

页码：63 / 75

页数：13

共 19 条

[1] ARRHENIUS G, 1985, COLLOQ INT CNRS, V289, P333
[2] SOL-GEL SYNTHESIS OF MANGANESE OXIDES
BACH, S
HENRY, M
BAFFIER, N
LIVAGE, J
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1990, 88 (02) : 325 - 333
[3] BIRNESSITE MANGANESE-DIOXIDE SYNTHESIZED VIA A SOL-GEL PROCESS - A NEW RECHARGEABLE CATHODIC MATERIAL FOR LITHIUM BATTERIES
BACH, S
PEREIRARAMOS, JP
BAFFIER, N
MESSINA, R
[J]. ELECTROCHIMICA ACTA, 1991, 36 (10) : 1595 - 1603
[4] CHUKHROV FV, 1978, INVESTIYA AKAD NAU G, V9, P67
[5] GABANO JP, 1985, Patent No. 8501309
[6] GIOVANOLI R, 1954, HELV CHIM ACTA, V37, P2322
[7] GIOVANOLI R, 1985, COLLOQ INT CNRS, V289, P305
[8] ION-EXCHANGE, THERMAL TRANSFORMATIONS, AND OXIDIZING PROPERTIES OF BIRNESSITE
GOLDEN, DC
DIXON, JB
CHEN, CC
[J]. CLAYS AND CLAY MINERALS, 1986, 34 (05) : 511 - 520
[9] AVAILABLE OXYGEN IN MANGANESE DIOXIDE
KATZ, MJ
CLARKE, RC
NYE, WF
[J]. ANALYTICAL CHEMISTRY, 1956, 28 (04) : 507 - 508
[10] LEGOFF P, 1994, J MATER CHEM, V4, P875

← 1 2 →