Hybrid organic-inorganic polyoxometalates:: Functionalization of VIV/VV nanosized clusters to produce molecular capsules

被引：155

作者：

Breen, John M. ^{[1
]}

Schmitt, Wolfgang ^{[1
]}

机构：

[1] Univ Dublin Trinity Coll, Sch Chem, Ctr Synth & Chem Biol, Dublin D2, Ireland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 36期

基金：

爱尔兰科学基金会;

关键词：

cluster compounds; coordination compounds; polyoxometalates; supramolecular chemistry; vanadium;

D O I：

10.1002/anie.200801770

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

(Figure Presented) Functionalization of polyoxovanadate clusters using phosphonate and arsonate ligands results in molecular capsules (see structure; green V, purple P, red O, black C). Through the use of extended homologous ligands, these hybrid organic-inorganic capsules can be successively elongated into tubular molecules. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6904 / 6908

页数：5

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