Reaction between methane and carbon dioxide to produce syngas in dielectric barrier discharge system

被引：20

作者：

Kim, Tae Kyung ^{[1
]}

Lee, Won Gyu ^{[1
]}

机构：

[1] Kangwon Natl Univ, Dept Chem Engn, Chuncheon Si 200701, Kangwon Do, South Korea

来源：

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY | 2012年 / 18卷 / 05期

基金：

新加坡国家研究基金会;

关键词：

Syngas; Dielectric barrier discharge; Carbon dioxide; Methane; Plasma reaction; SYNTHESIS GAS; PLASMA; CONVERSION; CATALYSTS;

D O I：

10.1016/j.jiec.2012.03.009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The conversion of CH4 and CO2 to syngas in a dielectric barrier discharge reactor was performed. The conversion to syngas increased with input power and decreased with total flow rate, whereas the selectivity of H-2 and CO did not change significantly. When CH4/CO2 ratio increased, the conversion of CH4 and the selectivity of H-2 and CO decreased. The highest conversion of CH4 and CO2 was 77.72% and 67.88%, respectively. It was confirmed that the DBD system can be used for producing syngas with the controllability in H-2/CO ratio. (C) 2012 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

引用

页码：1710 / 1714

页数：5

共 16 条

[1] Microwave-assisted dry reforming of methane [J].

Fidalgo, B. ;

Dominguez, A. ;

Pis, J. J. ;

Menendez, J. A. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (16) :4337-4344

[2] Plasma Thermal Conversion of Methane to Acetylene [J].

Fincke J.R. ;

Anderson R.P. ;

Hyde T. ;

Detering B.A. ;

Wright R. ;

Bewley R.L. ;

Haggard D.C. ;

Swank W.D. .

Plasma Chemistry and Plasma Processing, 2002, 22 (1) :105-136

[3]

Fischer F., 1928, BRENNST CHEM, P39

[4] Use of a non-thermal plasma for the production of synthesis gas from biogas [J].

Goujard, Valentin ;

Tatibouet, Jean-Michel ;

Batiot-Dupeyrat, Catherine .

APPLIED CATALYSIS A-GENERAL, 2009, 353 (02) :228-235

[5] Plasma catalytic hybrid processes: gas discharge initiation and plasma activation of catalytic processes [J].

Hammer, T ;

Kappes, T ;

Baldauf, M .

CATALYSIS TODAY, 2004, 89 (1-2) :5-14

[6] CO2 reforming of CH4 by atmospheric pressure ac discharge plasmas [J].

Huang, AM ;

Xia, GG ;

Wang, JY ;

Suib, SL ;

Hayashi, Y ;

Matsumoto, H .

JOURNAL OF CATALYSIS, 2000, 189 (02) :349-359

[7] Co-generation of synthesis gas and C2+ hydrocarbons from methane and carbon dioxide in a hybrid catalytic-plasma reactor:: A review [J].

Istadi ;

Amin, NAS .

FUEL, 2006, 85 (5-6) :577-592

[8] Some temperature effects on stability and carbon formation in low temperature ac plasma conversion of methane [J].

Le, H ;

Lobban, LL ;

Mallinson, RG .

CATALYSIS TODAY, 2004, 89 (1-2) :15-20

[9] Atmospheric Pressure Plasma Jet Composed of Three Electrodes: Application to Tooth Bleaching [J].

Lee, Hyun Woo ;

Nam, Seoul Hee ;

Mohamed, Abdel-Aleam H. ;

Kim, Gyoo Cheon ;

Lee, Jae Koo .

PLASMA PROCESSES AND POLYMERS, 2010, 7 (3-4) :274-280

[10] CO2 reforming of CH4 by atmospheric pressure glow discharge plasma: A high conversion ability [J].

Li, Daihong ;

Li, Xiang ;

Bai, Meigui ;

Tao, Xumei ;

Shang, Shuyong ;

Dai, Xiaoyan ;

Yin, Yonyxiang .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (01) :308-313

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