Polarization-Dependent Surface-Enhanced Raman Scattering from a Silver-Nanoparticle-Decorated Single Silver Nanowire

被引：130

作者：

Lee, Seung Joon ^{[1
]}

Baik, Jeong Min ^{[1
]}

Moskovits, Martin ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

NANO LETTERS | 2008年 / 8卷 / 10期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1021/nl801603j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single silver nanowires produced by DC electrodeposition in porous anodic alumina templates were surface-functionalized with the bifunctional molecule 4-aminobenzenthiol (ABT) then exposed to aqueous silver nanoparticles resulting in a silver nanoparticle-decorated silver nanowire. The polarization dependent surface-enhanced Raman (SERS) signal from this system showed significant intensity anisotropy when measured at a midsection of the nanowire, where the largest SERS intensities were observed when the incident light was polarized perpendicular to the nanowire's long axis but was almost isotropic near the tip of the nanowire. The observed effects were accounted for in terms of the electromagnetic fields concentrated in the collection of hot spots created through the ABT-linker-driven nanoparticle-nanowire self-assembly process.

引用

页码：3244 / 3247

页数：4

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