Efficient Oxidation of Methane to Methanol by Dioxygen Mediated by Tricopper Clusters

被引：149

作者：

Chan, Sunney I. ^{[1
]}

Lu, Yu-Jhang ^{[1
]}

Nagababu, Penumaka ^{[1
]}

Maji, Suman ^{[1
]}

Hung, Mu-Cheng ^{[1
]}

Lee, Marianne M. ^{[2
]}

Hsu, I-Jui ^{[3
]}

Pham Dinh Minh ^{[1
]}

Lai, Jeff C. -H. ^{[1
]}

Ng, Kok Yoah ^{[1
]}

Ramalingam, Sridevi ^{[2
]}

Yu, Steve S. -F. ^{[1
]}

Chan, Michael K. ^{[2
]}

机构：

[1] Acad Sinica, Inst Chem, Taipei 11529, Taiwan

[2] Ohio State Univ, Dept Chem & Biochem, Columbus, OH 43210 USA

[3] Natl Taipei Univ Technol, Dept Mol Sci & Engn, Taipei 10608, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 13期

基金：

美国国家科学基金会;

关键词：

biocatalysis; bioinorganic chemistry; catalysis; C-H activation; tricopper complex; CATALYTIC CONVERSION; ATOM TRANSFER; HYDROCARBONS; MONOOXYGENASE; TEMPERATURE; MORDENITE;

D O I：

10.1002/anie.201209846

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

TONs of copper fun: There is considerable interest in developing catalysts to harness the abundant natural supply of methane for various industrial applications. Two tricopper complexes capable of mediating efficient oxidation of methane to methanol under ambient conditions were tested: a biomimetic tricopper complex (see figure) and a tricopper-peptide species derived from the particulate methane monooxygenase (pMMO) protein. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：3731 / 3735

页数：5

共 21 条

[1]

Catalytic conversion of methane to methanol over Cu-mordenite [J].