Room temperature synthesis of metal-organic frameworks: MOF-5, MOF-74, MOF-177, MOF-199, and IRMOF-0

被引：864

作者：

Tranchemontagne, David J. ^{[1
]}

Hunt, Joseph R. ^{[1
]}

Yaghi, Omar M. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Calif NanoSyst Inst, Ctr Reticular Chem, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

TETRAHEDRON | 2008年 / 64卷 / 36期

关键词：

D O I：

10.1016/j.tet.2008.06.036

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Room temperature synthesis of metal-organic frameworks (MOFs) has been developed for four well-known MOFs: MCF-5, MOF-74, MOF-177, and MOF-199. A new isoreticular metal framework (IRMOF), IRMOF-0, having the same cubic topology as MOF-5, has been synthesized from acetylenedicarboxylic acid using this method to accommodate the thermal sensitivity of the linker. Despite acetylenedi-carboxylate being the shortest straight linker that can be made into an IRMOF, IRMOF-0 forms as a doubly interpenetrating structure, owing to the rod-like nature of the linker. (C) 2008 Elsevier Ltd. All rights reserved.

引用

页码：8553 / 8557

页数：5

共 24 条

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