Mechanisms of electrochemical recognition of cations, anions and neutral guest species by redox-active receptor molecules

被引：283

作者：

Beer, PD

Gale, PA

Chen, GZ

机构：

[1] Univ Oxford, Inorgan Chem Lab, Dept Chem, Oxford OX1 3QR, England

[2] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England

来源：

COORDINATION CHEMISTRY REVIEWS | 1999年 / 185-6卷

关键词：

electrochemistry; molecular recognition; sensors; supramolecular chemistry;

D O I：

10.1016/S0010-8545(98)00246-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This short review highlights the mechanisms involved in electrochemically sensing cationic, anionic and neutral guest species by redox-active receptors and is an update to a previously published review article (P.D. Beer, P.A. Gale, Z. Chen, Adv. Phys. Org. Chem. 31 (1998) 1). Mechanisms of redox-complexation coupling are discussed together with recent examples of redox-responsive molecular receptors from the literature that illustrate them. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：3 / 36

页数：34

共 40 条

[1] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A NEW REDOX-ACTIVE CALIX[5]ARENE CONTAINING A TOTALLY INCLUDED ETHANOL MOLECULE
BEER, PD
CHEN, Z
DREW, MGB
GALE, PA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (18) : 1851 - 1852
[2] New ionophoric calix[4]diquinones: Coordination chemistry, electrochemistry, and X-ray crystal structures
Beer, PD
Gale, PA
Chen, Z
Drew, MGB
Heath, JA
Ogden, MI
Powell, HR
[J]. INORGANIC CHEMISTRY, 1997, 36 (25) : 5880 - 5893
[3] Anion selective recognition and optical/electrochemical sensing by novel transition-metal receptor systems
Beer, PD
[J]. CHEMICAL COMMUNICATIONS, 1996, (06) : 689 - 696
[4] Transition metal cation and phosphate anion electrochemical recognition in water by new polyaza ferrocene macrocyclic ligands
Beer, PD
Chen, Z
Drew, MGB
Johnson, AOM
Smith, DK
Spencer, P
[J]. INORGANICA CHIMICA ACTA, 1996, 246 (1-2) : 143 - 150
[5] NEW POLYAZA AND POLYAMMONIUM FERROCENE MACROCYCLIC LIGANDS THAT COMPLEX AND ELECTROCHEMICALLY RECOGNIZE TRANSITION-METAL CATIONS AND PHOSPHATE ANIONS IN WATER
BEER, PD
CHEN, Z
DREW, MGB
KINGSTON, J
OGDEN, M
SPENCER, P
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (13) : 1046 - 1048
[6] Electrochemical recognition of charged and neutral guest species by redox-active receptor molecules
Beer, PD
Gale, PA
Chen, Z
[J]. ADVANCES IN PHYSICAL ORGANIC CHEMISTRY, VOL 31, 1998, 31 : 1 - 90
[7] Tunable bis(ferrocenyl) receptors for the solution-phase electrochemical sensing of transition-metal cations
Beer, PD
Smith, DK
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (03): : 417 - 423
[8] Neutral ferrocenoyl receptors for the selective recognition and sensing of anionic guests
Beer, PD
Graydon, AR
Johnson, AOM
Smith, DK
[J]. INORGANIC CHEMISTRY, 1997, 36 (10) : 2112 - 2118
[9] Selective electrochemical recognition of bidentate anionic guests in competitive solvents using novel ferrocenyl thiourea and guanidinium receptors
Beer, PD
Drew, MGB
Smith, DK
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 543 (1-2) : 259 - 261
[10] A NEW BIPYRIDINIUM BIS BENZO CROWN-ETHER LIGAND WHOSE REDOX PROPERTIES ARE DEPENDENT UPON COMPLEXED CATION-INDUCED CONFORMATIONAL SWITCHING EFFECTS
BEER, PD
CHEN, Z
GRIEVE, A
HAGGITT, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (20) : 2413 - 2414

← 1 2 3 4 →