Enantiopure pseudo-C3-symmetric titanium alkoxide with propeller-like chirality

被引：45

作者：

Axe, Philip

Bull, Steven D. ^{[1
]}

Davidson, Matthew G.

Gilfillan, Carly J.

Jones, Matthew D.

Robinson, Diane E. J. E.

Turner, Luke E.

Mitchell, William L.

机构：

[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[2] GSK PLC, Harlow CM19 5AW, Essex, England

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 02期

关键词：

D O I：

10.1021/ol062655w

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An enantiopure amine tris(phenolate) ligand containing a single stereogenic center has been used to control the propeller-like chirality of a derived pseudo-C-3-symmetric titanium isopropoxide complex with excellent levels of diastereocontrol.

引用

页码：223 / 226

页数：4

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