Block-selected molecular recognition and formation of polypseudorotaxanes between poly(propylene oxide)-poly (ethylene oxide)poly(propylene oxide) triblock copolymers and α-cyclodextrin

被引：83

作者：

Li, J

Ni, XP

Leong, K

机构：

[1] Inst Mat Res & Engn, Singapore 117602, Singapore

[2] Natl Univ Singapore, Fac Engn, Div Bioengn, Singapore 117576, Singapore

[3] Johns Hopkins Univ, Dept Biomed Engn, Baltimore, MD 21205 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 01期

关键词：

D O I：

10.1002/anie.200390055

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Although a poly(propylene oxide) (PPO) chain was previously thought to be impenetrable to α-cyclodextrin, the middle poly(ethylene oxide) (PEO) block of PPO-PEO-PPO triblock copolymers can be selectively recognized and included by α-cyclodextrin to form polypseudorotaxanes (see schematic representation), even though it is flanked by two PPO blocks.

引用

页码：69 / 72

页数：4

共 36 条

[21]

NOSTRO PL, 2001, LANGMUIR, V17, P4610

[22] Inclusion complexes of chain molecules with cycloamyloses -: III.: Molecular dynamics simulations of polyrotaxanes formed by poly(propyleneglycol) and β-cyclodextrins [J].