Modification of β-cyclodextrin with ferrocenyl groups by ring opening of an encapsulated [1]ferrocenophane

被引：25

作者：

Ferreira, P ^{[1
]}

Gonçalves, IS ^{[1
]}

Pillinger, M ^{[1
]}

Rocha, J ^{[1
]}

Santos, P ^{[1
]}

Teixeira-Dias, JJC ^{[1
]}

机构：

[1] Univ Aveiro, Dept Quim, P-3810193 Aveiro, Portugal

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 08期

关键词：

D O I：

10.1021/om991033u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

beta-Cyclodextrin covalently grafted with ferrocenyl groups is obtained after formation of a 2:1 (host to guest) complex between beta-CD and (1,1'-ferrocenediyl)dimethylsilane. Structural investigation in the solid state confirms -OH attack of the strained C-Si-C bridge to form an O-Si bond.

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收藏

页码：1455 / 1457

页数：3

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