Synthesis, characterization and electrochemical studies of LiNiVO4 cathode material in rechargeable lithium batteries

被引:48
作者
Chitra, S
Kalyani, P
Yebka, B
Mohan, T
Haro-Poniatowski, E
Gangadharan, R
Julien, C
机构
[1] Univ Paris 06, CNRS, Lab Mileux Desordonnes & Heterogenes, UMR 7603, F-75252 Paris 05, France
[2] Cent Electrochem Res Inst, Karaikudi 630006, Tamil Nadu, India
关键词
lithium vanadate; Raman; FTIR; lithium batteries; kinetics;
D O I
10.1016/S0254-0584(99)00243-6
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
High voltage cathode composite LiNiVO4 was synthesized in a very pure state by a new inorganic synthetic procedure. The structural properties of this compound were characterized by X-ray diffraction and vibrational spectroscopies, Its suitability was tested by fabricating a lithium cell in non-aqueous media and the electrochemical parameters (i.e., cyclability, chemical diffusion coefficient of Li ions and enhancement factor) were studied. (C) 2000 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:32 / 37
页数:6
相关论文
共 26 条
[1]  
BERNIER JC, 1961, CR HEBD ACAD SCI, V253, P1578
[2]  
CHEN LQ, 1993, SOLID STATE IONICS, V67, P17, DOI 10.1016/0167-2738(93)90303-K
[3]  
CHITRA S, 1999, IN PRESS COMBUSTION
[4]   LINIVO4 - A 4.8 VOLT ELECTRODE MATERIAL FOR LITHIUM CELLS [J].
FEY, GTK ;
LI, W ;
DAHN, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (09) :2279-2282
[5]   A new preparation method for a novel high voltage cathode material: LiNiVO4 [J].
Fey, GTK ;
Perng, W .
MATERIALS CHEMISTRY AND PHYSICS, 1997, 47 (2-3) :279-282
[6]   The effects of the stoichiometry and synthesis temperature on the preparation of the inverse spinel LiNiVO4 and its performance as a new high voltage cathode material [J].
Fey, GTK ;
Dahn, JR ;
Zhang, MJ ;
Li, W .
JOURNAL OF POWER SOURCES, 1997, 68 (02) :549-552
[7]   New inverse spinel cathode materials for rechargeable lithium batteries [J].
Fey, GTK ;
Wang, KS ;
Yang, SM .
JOURNAL OF POWER SOURCES, 1997, 68 (01) :159-165
[8]  
FEY GTK, 1996, 8 INT M LITH BATT, P143
[9]  
FEY GTK, 1996, 8 INT M LITH BATT, P426
[10]   THE CARBON LI1+XMN2O4 SYSTEM [J].
GUYOMARD, D ;
TARASCON, JM .
SOLID STATE IONICS, 1994, 69 (3-4) :222-237