Generation of three isomers of C7H- in the gas phase.: A joint experimental and theoretical study

被引：4

作者：

Dua, S ^{[1
]}

Bowie, JH ^{[1
]}

Blanksby, SJ ^{[1
]}

机构：

[1] Univ Adelaide, Dept Chem, Adelaide, SA 5005, Australia

来源：

EUROPEAN MASS SPECTROMETRY | 1999年 / 5卷 / 05期

关键词：

circumstellar molecules; three isomers of C7H-; neutral HC2C(C-2)(2);

D O I：

10.1255/ejms.290

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Three anion isomers of formula C7H have been synthesised in the mass spectrometer by unequivocal routes. The structures of the isomers are [HCCC(C-2)(2)](-), C6CH- and C2CHC4-. One of these, [HCCC(C-2)(2)](-), is formed in sufficient yield to allow it to be charge stripped to the corresponding neutral radical.

引用

收藏

页码：309 / 317

页数：9

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