Methyltris(pyrazolyl)silanes: new tripodal nitrogen-donor ligands

被引：22

作者：

Pullen, EE

Rheingold, AL

Rabinovich, D

机构：

[1] Univ N Carolina, Dept Chem, Charlotte, NC 28223 USA

[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 05期

关键词：

pyrazoles; silanes; crystal structures; copper(I) complexes;

D O I：

10.1016/S1387-7003(99)00046-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two tridentate nitrogen-donor ligands, the methyltris(pyrazolyl) silanes MeSi(3,5-RR'pz)(3) (R = R' = Me; R = Bu-t, R' = Ii), have been synthesized and the X-ray structure of the latter has been determined. The first transition metal derivatives of these ligands, the cationic copper( I) complexes [LCu(NCMe)](+) (where L = MeSi(3.5-Me(2)pz)(3) or MeSi(3-Bu'pz)(3)). have been prepared and characterized analytically and spectroscopically. (C) 1999 Elsevier Science S.A. All rights reserved.

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页码：194 / 196

页数：3

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