Spectral-line-broadening study of the trivalent lanthanide-ion series .2. The variation of the electron-phonon coupling strength through the series

The variation of an electron-phonon coupling strength of lanthanide ions is evaluated by measuring the temperature-dependent line broadening of a large number of 4f transitions of nine lanthanide ions. The results show that the electron-phonon coupling strength derived from these line-broadening experiments is large in the beginning (Ce3+,Pr3+,Nd3+) and the end (Er3+,Tm3+,Yb3+) of the trivalent lanthanide-ion series, but small at the center (Eu3+,Gd3+,Tb3+). This trend can qualitatively be explained by the lanthanide contraction and the shielding of the 4f electrons.