RuHCl(CO)(PPh3)3-catalyzed chemoselective transfer-hydrogenation of enones leading to saturated ketones

被引：42

作者：

Doi, T ^{[1
]}

Fukuyama, T ^{[1
]}

Horiguchi, J ^{[1
]}

Okamura, T ^{[1
]}

Ryu, I ^{[1
]}

机构：

[1] Osaka Prefecture Univ, Dept Chem, Grad Sch Sci, Sakai, Osaka 5998531, Japan

来源：

SYNLETT | 2006年 / 05期

关键词：

transfer-hydrogenation; enones; ruthenium hydride complexes; ketones; chemoselective;

D O I：

10.1055/s-2006-933133

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The highly chemoselective transfer-hydrogenation of alpha,beta-unsaturated ketones to give saturated ketones was achieved using RuHCl(CO)(PPh3)(3) as a catalyst. In addition to alpha,beta-unsaturated ketones, other enones, containing a remote C=C bond, were also reduced to give saturated ketones in good to excellent yields with high selectivity.

引用

页码：721 / 724

页数：4

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