Fast pyrolysis of biomass in free-fall reactor for hydrogen-rich gas

被引：421

作者：

Li, SG ^{[1
]}

Xu, SP ^{[1
]}

Liu, SQ ^{[1
]}

Yang, C ^{[1
]}

Lu, QH ^{[1
]}

机构：

[1] Dalian Univ Technol, Sch Chem, Inst Coal Chem Engn, Dalian 116012, LiaoNing, Peoples R China

来源：

FUEL PROCESSING TECHNOLOGY | 2004年 / 85卷 / 8-10期

关键词：

biomass; fast pyrolysis; free-fall reactor; hydrogen-rich gas;

D O I：

10.1016/j.fuproc.2003.11.043

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Fast pyrolysis of two typical biomasses (legume straw and apricot stone) in a free-fall reactor was studied. The pyrolysis behavior of the biomass is strongly relevant to its chemical composition. Under fast heating and pyrolysis conditions as in the free-fall reactor, an interaction of the biomass pyrolysis with the in situ steam reforming of the pyrolysis intermediate products occurs, which leads to more hydrogen-rich gas yield. The total ratio of CO and H-2 in the gas product reaches 65.4 mol% for legume straw and 55.7 mol% for apricot stone, respectively. Effects of sample particle size and pyrolysis temperature on the fast pyrolysis of the biomass were also studied. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1201 / 1211

页数：11