Tar removal from biosyngas in the biomass gasification process. (Liquid plus liquid) equilibrium {water plus solvent (paraxylene and methyl hexadecanoate) plus model molecules of tar (benzene, toluene, phenol)}

被引:21
作者
Bassil, Georgio [1 ]
Mokbel, Ilham [1 ]
Abou Naccoul, Ramy [1 ]
Stephan, Juliette
Jose, Jacques [1 ]
Goutaudier, Christelle [2 ]
机构
[1] Univ Lyon 1, Equipe Thermodynam Analyse & Proc UMR 5280, F-69622 Villeurbanne, France
[2] Univ Lyon 1, Labs Multimat & Interfaces, UMR 5615, F-69622 Villeurbanne, France
关键词
(Liquid plus liquid) equilibria; Methyl palmitate; Paraxylene; Benzene; Toluene; Phenol; Molar fraction; Methyl hexadecanoate; MUTUAL SOLUBILITIES; P-XYLENE; MIXTURES; DECOMPOSITION; SYSTEMS; ENERGY;
D O I
10.1016/j.jct.2011.12.009
中图分类号
O414.1 [热力学];
学科分类号
070201 [理论物理];
摘要
Tar is generated in the process by the condensation of the gas resulting from biomass gasification. The objective of this work is a contribution to the database on thermodynamic quantity which will be useful at the operation of tar removal from aqueous medium. With this aim, (liquid + liquid) equilibrium of {water + solvent (paraxylene and methyl hexadecanoate) + model molecules of tar (benzene, toluene, phenol)} was studied at temperatures (303.2, 323.2, and 343.2) K. The data obtained were correlated with the non-random two-liquid (NRTL) model. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:123 / 128
页数:6
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