Synthesis of a chiral molecular square with two organic corners

被引:12
作者
Harmata, M [1 ]
Kahraman, M [1 ]
机构
[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0040-4039(99)00725-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The bipyridyl ligand 5 was readily prepared in enantiomerically-pure form by coupling the appropriate stannanes with the bis-triflate 3. Mixing this ligand with a palladium ditriflate resulted in the formation of a chiral molecular square, according to spectroscopic analysis. (C) 1999 Elsevier Science Ltd. All rights reserved.
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页码:4133 / 4136
页数:4
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