Novel oxo-bridged blue luminescent organoaluminum complexes: Al-4(CH3)(6)(mu(3)-O)(2)(dpa)(2) and Al-3(7-azain)(4)(OCH(CF3)(2))(2)(CH3)(mu(3)-O) (dpa = deprotonated di-2-pyridylamine, 7-azain = deprotonated 7-azaindole)

被引：75

作者：

Liu, W ^{[1
]}

Hassan, A ^{[1
]}

Wang, SN ^{[1
]}

机构：

[1] QUEENS UNIV,DEPT CHEM,KINGSTON,ON K7L 3N6,CANADA

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 20期

关键词：

D O I：

10.1021/om9706020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel blue luminescent organoaluminum complexes Al-4(CH3)(6)(mu(3)-O)(2)(dpa)(2) (1) and Al-3(7-azain)(4)(OCH(CF3)(2))(2)(CH3)(mu(3)-O) (2) (dpa = deprotonated di-2-pyridylamine, 7-azain = deprotonated 7-azaindole) have been synthesized and characterized structurally. The unusual stability of these compounds is attributed to the presence of the triply-bridging oxo ligand.

引用

页码：4257 / 4259

页数：3

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