A mild, copper catalyzed route to conducting polyaniline

被引:48
作者
Dias, HVR [1 ]
Wang, XY
Rajapakse, RMG
Elsenbaumer, RL
机构
[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA
[2] Univ Peradeniya, Dept Chem, Peradeniya, Sri Lanka
关键词
D O I
10.1039/b513938d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The aniline dimer, N-(4-aminophenyl)aniline has been polymerized cleanly under mild conditions to obtain an emeraldine base form of polyaniline using [MeB(3-(Mes)Pz)3]CuCl as the catalyst and H(2)O(2) as the oxidant, while the subsequent acidification of the emeraldine base gives the conducting emeraldine salt form of polyaniline.
引用
收藏
页码:976 / 978
页数:3
相关论文
共 28 条
[1]   SPECTROSCOPIC AND ELECTROCHEMICAL STUDIES OF CHARGE-TRANSFER IN MODIFIED ELECTRODES [J].
ALBERY, WJ ;
CHEN, Z ;
HORROCKS, BR ;
MOUNT, AR ;
WILSON, PJ ;
BLOOR, D ;
MONKMAN, AT ;
ELLIOTT, CM .
FARADAY DISCUSSIONS, 1989, 88 :247-+
[2]   DUAL TRANSMISSION-LINE WITH CHARGE-TRANSFER RESISTANCE FOR CONDUCTING POLYMERS [J].
ALBERY, WJ ;
MOUNT, AR .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1994, 90 (08) :1115-1119
[3]  
ALBERY WJ, 1994, ELECTROACTIVE POLYM, V1, P443
[4]   The inductive behavior derived from hydrolysis of polyaniline [J].
Chen, WC ;
Wen, TC ;
Gopalan, A .
ELECTROCHIMICA ACTA, 2002, 47 (26) :4195-4206
[5]   Study of the interconversion of polyaniline oxidation states by optical absorption spectroscopy [J].
de Albuquerque, JE ;
Mattoso, LHC ;
Faria, RM ;
Masters, JG ;
MacDiarmid, AG .
SYNTHETIC METALS, 2004, 146 (01) :1-10
[6]  
ELSEMBAUMER RL, 1992, Patent No. 5160457
[7]   VIBRATIONAL-SPECTRA AND STRUCTURE OF POLYANILINE [J].
FURUKAWA, Y ;
UEDA, F ;
HYODO, Y ;
HARADA, I ;
NAKAJIMA, T ;
KAWAGOE, T .
MACROMOLECULES, 1988, 21 (05) :1297-1305
[8]   Highly regioselective oxidative polymerization of 4-phenoxyphenol to poly(1,4-phenylene oxide) catalyzed by tyrosinase model complexes [J].
Higashimura, H ;
Fujisawa, K ;
Moro-oka, Y ;
Kubota, M ;
Shiga, A ;
Terahara, A ;
Uyama, H ;
Kobayashi, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (33) :8529-8530
[9]   Radical-controlled oxidative polymerization of 4-phenoxyphenol by a tyrosinase model complex catalyst to poly(1,4-phenylene oxide) [J].
Higashimura, H ;
Kubota, M ;
Shiga, A ;
Fujisawa, K ;
Moro-oka, Y ;
Uyama, H ;
Kobayashi, S .
MACROMOLECULES, 2000, 33 (06) :1986-1995
[10]   A powerful electrical network model for the impedance of mixed conductors [J].
Jamnik, J ;
Maier, J ;
Pejovnik, S .
ELECTROCHIMICA ACTA, 1999, 44 (24) :4139-4145