Redox Cofactor from Biological Energy Transduction as Molecularly Tunable Energy-Storage Compound

被引：150

作者：

Lee, Minah ^{[1
]}

Hong, Jihyun ^{[2
]}

Seo, Dong-Hwa ^{[2
]}

Nam, Dong Heon ^{[1
]}

Nam, Ki Tae ^{[2
]}

Kang, Kisuk ^{[2
]}

Park, Chan Beum ^{[1
]}

机构：

[1] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea

[2] Seoul Natl Univ, Res Inst Adv Mat, Dept Mat Sci & Engn, Inst Basic Sci,Ctr Nanoparticle Res, Seoul 151742, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 32期

基金：

新加坡国家研究基金会;

关键词：

bioenergetics; biomimetics; flavins; lithium battery; organic electrodes; GAUSSIAN-BASIS SETS; LI-ION BATTERIES; ELECTRON-TRANSFER; FLAVOENZYME ACTIVITY; MODEL SYSTEMS; ATOMS LI; X-RAY; RIBOFLAVIN; SPECTRA; REDUCTION;

D O I：

10.1002/anie.201301850

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Flavin Battery: Flavins are used as a molecularly tunable cathode material that reversibly reacts with two lithium ions and two electrons per formula unit. Combined ex situ analyses and DFT calculations reveal that the redox reaction occurs using two successive single-electron transfer steps at nitrogen atoms of the diazabutadiene motif (see picture). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8322 / 8328

页数：7

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