Polymeric [(Me3Sn)(3)Rh(SCN)(6)]: A novel ''super-Prussian-blue'' derivative containing the nonlinear-SCN-Sn-NCS-spacer

被引:35
作者
Siebel, E
Fischer, RD
机构
[1] Inst. Anorganische und Angew. Chem., Universität, D-20146 Hamburg
关键词
coordination polymers; Prussian blue; rhodium; structure elucidation; tin;
D O I
10.1002/chem.19970031213
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The new coordination polymer [(Me3SnIV)(3)Rh-III(SCN)(6)] = (3)(infinity)[Rh{mu-(SCNSnMe3NCS)}(3)] (5) is readily accessible by straightforward self-assembly of [Rh(SCN)(6)](3-) and (dehydrated) {Me3Sn}(aq)(+) ions. The architecture of 5 is strongly reminiscent of ''super-Prussian-blue'' systems reported earlier: there is a three-dimensional (3-D) framework involving {Rh-8} pseudocubes as the basic building blocks, the Rh3+ ions being held apart by novel, nonlinear {SCN-SnMe3NCS} spacers (d(Rh ... Rh) = 1.27 nm). The complete lattice consists of two equivalent and independent, ideally interwoven 3-D frameworks. Three homologues of 5 with slightly modified R3Sn units (R = Et, nPr and nBu) have been prepared as well, but display X-ray powder diffraction patterns notably different from that of 5.
引用
收藏
页码:1987 / 1991
页数:5
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