Graphene Hydrogels Deposited in Nickel Foams for High-Rate Electrochemical Capacitors

被引:426
作者
Chen, Ji [1 ]
Sheng, Kaixuan [1 ]
Luo, Peihui [1 ]
Li, Chun [1 ]
Shi, Gaoquan [1 ]
机构
[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China
关键词
electrochemical capacitors; electrodes; graphene; hydrogels; nickel foam; supercapacitors; DOUBLE-LAYER CAPACITORS; CARBON NANOTUBES; HIGH-PERFORMANCE; SUPERCAPACITORS; FILMS; OXIDE; ELECTRODES; SHEETS;
D O I
10.1002/adma.201201978
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene hydrogel/nickel foam composite electrodes for high-rate electrochemical capacitors are produced by reduction of an aqueous dispersion of graphene oxide in a nickel foam (upper half of figure). The micropores of the hydrogel are exposed to the electrolyte so that ions can enter and form electrochemical double-layers. The nickel framework shortens the distances of charge transfer. Therefore, the electrochemical capacitor exhibits highrate performance (see plots).
引用
收藏
页码:4569 / 4573
页数:5
相关论文
共 35 条
  • [1] Functional Composite Materials Based on Chemically Converted Graphene
    Bai, Hua
    Li, Chun
    Shi, Gaoquan
    [J]. ADVANCED MATERIALS, 2011, 23 (09) : 1089 - 1115
  • [2] R&D considerations for the performance and application of electrochemical capacitors
    Burke, Andrew
    [J]. ELECTROCHIMICA ACTA, 2007, 53 (03) : 1083 - 1091
  • [3] Electrochemical characterization of carbon nanotubes as electrode in electrochemical double-layer capacitors
    Chen, JH
    Li, WZ
    Wang, DZ
    Yang, SX
    Wen, JG
    Ren, ZF
    [J]. CARBON, 2002, 40 (08) : 1193 - 1197
  • [4] Chen ZP, 2011, NAT MATER, V10, P424, DOI [10.1038/NMAT3001, 10.1038/nmat3001]
  • [5] deLevie R., 1967, ADV ELECTROCHEMISTRY, V6, P329
  • [6] High power density supercapacitor electrodes of carbon nanotube films by electrophoretic deposition
    Du, Chunsheng
    Pan, Ning
    [J]. NANOTECHNOLOGY, 2006, 17 (21) : 5314 - 5318
  • [7] Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors
    El-Kady, Maher F.
    Strong, Veronica
    Dubin, Sergey
    Kaner, Richard B.
    [J]. SCIENCE, 2012, 335 (6074) : 1326 - 1330
  • [8] Hughes M, 2002, ADV MATER, V14, P382, DOI 10.1002/1521-4095(20020304)14:5<382::AID-ADMA382>3.0.CO
  • [9] 2-Y
  • [10] PREPARATION OF GRAPHITIC OXIDE
    HUMMERS, WS
    OFFEMAN, RE
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) : 1339 - 1339