Embracing C60 with multiarmed geodesic partners

被引：163

作者：

Mizyed, S

Georghiou, PE

Bancu, M

Cuadra, B

Rai, AK

Cheng, PC

Scott, LT ^{[1
]}

机构：

[1] Boston Coll, Merkert Chem Ctr, Dept Chem, Chestnut Hill, MA 02467 USA

[2] Mem Univ Newfoundland, Dept Chem, St Johns, NF A1B 3X7, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2001年 / 123卷 / 51期

关键词：

D O I：

10.1021/ja016761z

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,3,5,7,9-Pentakis(4-methoxyphenylthio)corannulene (3), 1,3,5,7,9-pentakis(2-naphthylthio)corannulene (4), and 1,3,6,8-tetrakis(4-methoxyphenylthio)corannulene (5b) have been synthesized by chlorination of corannulene with ICI in CH2Cl2 at 25 degreesC and subsequent nucleophilic aromatic substitution with the appropriate sodium thiophenolate in DMEU at 25 degreesC. H-1 NMR titration studies demonstrate that these novel bowl-shaped hosts form 1: 1 complexes with C-60 in toluene-d(8) solution with association constants of 454, 368, and 280 M-1, respectively.

引用

页码：12770 / 12774

页数：5

共 22 条

[1] PERCHLOROCORONENE - A NOVEL HOST PRECURSOR [J].