Metal-catalyzed transformation of D-glucal to optically active furan diol

被引：22

作者：

Hayashi, M ^{[1
]}

Kawabata, H ^{[1
]}

Yamada, K ^{[1
]}

机构：

[1] Yamaguchi Univ, Fac Sci, Dept Chem, Yamaguchi 7538512, Japan

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 11期

关键词：

D O I：

10.1039/a902510c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The treatment of D-glucal with a catalytic amount of Sm(OTf)(3) or RuCl2(PPh3)(3) in the presence of 1 equiv, of H2O afforded optically active furan diol in good yield under mild conditions.

引用

页码：965 / 966

页数：2

共 7 条

[1] RECENT ADVANCES IN FURAN CHEMISTRY .1. [J].

DEAN, FM .

ADVANCES IN HETEROCYCLIC CHEMISTRY, 1982, 30 :167-238

[2] CATALYSIS BY MERCURIC ION OF REACTIONS OF GLYCALS WITH WATER [J].

GONZALEZ, F ;

LESAGE, S ;

PERLIN, AS .

CARBOHYDRATE RESEARCH, 1975, 42 (02) :267-274

[3] Hydrogen transfer of D-glycals by palladium complexes under ethylene atmosphere [J].

Hayashi, M ;

Yamada, K ;

Arikita, O .

TETRAHEDRON LETTERS, 1999, 40 (06) :1171-1174

[4]

LICHTENTHALER FW, 1992, MODERN SYNTHETIC MET, V6, P273

[5]

TOLSTIKOV NV, 1988, SYNTHESIS-STUTTGART, P221

[6]

WALCZAK K, 1991, SYNTHESIS-STUTTGART, P959

[7]

WENGEL J, 1989, SYNTHESIS-STUTTGART, P829

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