Glendonites as a paleoenvironmental tool: Implications for early Cretaceous high latitude climates in Australia

Glendonites, calcite pseudomorphs after the metastable mineral ikaite (CaCO3. 6H(2)O), occur in the Late Aptian interval of the Bulldog Shale in the Eromanga Basin, Australia and in other Early Cretaceous basins at high paleolatitudes. Ikaite precipitation in the marine environment requires near-freezing temperatures (not higher than 4 degrees C), high alkalinity, increased levels of orthophosphate, and high P-CO2. The rapid and complete transformation of ikaite to calcite at temperatures between 5 and 8 degrees C provides an upper limit on the oxygen isotopic composition of the pore waters: -2.6 < delta(2) < -3.4 parts per thousand SMOW. If it is assumed that these pore waters are representative of the shallow Eromanga Basin, the calculated delta(w) can be used to reassess belemnite fossil oxygen isotopic paleotemperatures-temperature recorded by fauna living in the basin at the time of ikaite precipitation. Data previously reported as 11 to 16 degrees C (assuming delta(w) = 0.0 parts per thousand SMOW) yield paleotemperatures ranging from -1 to 5 degrees C, squarely in the range of ikaite stability. The low delta(w) indicates hyposaline conditions, most likely caused by mixing high latitude meteoric waters with seawater. The O-18 depleted, low temperature waters suggest that the region was at least seasonally colder than previously accepted. Copyright (C) 1999 Elsevier Science Ltd.