Fluorous-phase soluble rhodium complexes: X-ray structure of [RhCl(CO)(P(C2H4C6F13)(3))(2)]

被引:42
作者
Fawcett, J
Hope, EG
Kemmitt, RDW
Paige, DR
Russell, DR
Stuart, AM
ColeHamilton, DJ
Payne, MJ
机构
[1] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND
[2] UNIV ST ANDREWS,SCH CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND
关键词
D O I
10.1039/a702560b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rhodium(I) complexes of the ligands P(CH2CH2C6F13)(3) and P(C6H4C6F13-4)(3), which can be compared to their perprotio analogues, maintain their structures in fluorous solvents.
引用
收藏
页码:1127 / 1128
页数:2
相关论文
共 17 条
  • [1] Carbon-fluorine and -hydrogen bond activation and carbon-carbon bond formation in eta(5)-pentamethylcyclopentadienyl-rhodium and -iridium phosphine complexes; Crystal structures of [M(eta(5)-C(5)Me(5))Cl{(C6F5)(2)PCH2CH2P-(C6F5)(2)}](BF4-)-B-+ (M=Rh or Ir)
    Atherton, MJ
    Fawcett, J
    Holloway, JH
    Hope, EG
    Karacar, A
    Russell, DR
    Saunders, GC
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (15): : 3215 - 3220
  • [2] Pentafluorophenylphosphine complexes of Rhodium(I): Extended x-ray absorption fine structure studies of [{Rh[PPh(x)(C6F5)(3-x)](2)(mu-Cl)}(n)] (x=0-2) and [{Rh[(C6F5)(2)PCH2CH2P(C6F5)(2)](mu-Cl)}(2)]. Crystal structures of [RhCl(PPh(3)){(C6F5)(2)PCH2CH2P(C6F5)(2)}]center dot C4H8O and (C6F5)(2)PCH2CH2P(C6F5)(2)
    Atherton, MJ
    Coleman, KS
    Fawcett, J
    Holloway, JH
    Hope, EG
    Karacar, A
    Peck, LA
    Saunders, GC
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (24): : 4029 - 4037
  • [3] BHATTACHARYA PK, UNPUB
  • [4] Scanning and energy dispersive EXAFS studies of ethyl transmetallation in an alkene oligomerisation catalyst
    Bogg, D
    Conyngham, M
    Corker, JM
    Dent, AJ
    Evans, J
    Farrow, RC
    Kambhampati, VL
    Masters, AF
    McLeod, DN
    Ramsdale, CA
    Salvini, G
    [J]. CHEMICAL COMMUNICATIONS, 1996, (05) : 647 - 648
  • [5] SYNTHESIS AND CHARACTERIZATION OF RH(P(CH3)3)2(CO)CH3 AND RH(P(CH3)3)2(CO)PH
    BOYD, SE
    FIELD, LD
    HAMBLEY, TW
    PARTRIDGE, MG
    [J]. ORGANOMETALLICS, 1993, 12 (05) : 1720 - 1724
  • [6] SYNTHESIS AND CHARACTERIZATION OF IRIDIUM-CARBONYL FLUORIDES
    BREWER, SA
    BRISDON, AK
    HOLLOWAY, JH
    HOPE, EG
    PECK, LA
    WATSON, PG
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (18): : 2945 - 2948
  • [7] THE CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-CHLOROCARBONYLBIS(TRIPHENYLPHOSPHINE)RHODIUM(I) IN ITS MONOCLINIC FORM
    CERIOTTI, A
    CIANI, G
    SIRONI, A
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 247 (03) : 345 - 350
  • [8] RHODIUM(1) AND RHODIUM(3) CARBONYL COMPLEXES CONTAING TERTIARY PHOSPHINES OR TERTIARY ARSINES AND HALOGEN FORMED BY DECARBONYLATION OF ALCOHOLS AND BY DIRECT USE OF CARBON MONIXIDE
    CHATT, J
    SHAW, BL
    [J]. JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1966, (10): : 1437 - &
  • [9] STRUCTURAL CHARACTERIZATION OF SOLUTION SPECIES IMPLICATED IN THE RHODIUM-CATALYZED CARBONYLATION OF METHANOL BY RH K-EDGE X-RAY-ABSORPTION SPECTROSCOPY
    CRUISE, NA
    EVANS, J
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (18): : 3089 - 3091
  • [10] Tris(2-(perfluorohexyl)ethyl)tin hydride: A new fluorous reagent for use in traditional organic synthesis and liquid phase combinatorial synthesis
    Curran, DP
    Hadida, S
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (10) : 2531 - 2532