Luminescence of Eu2+ in host lattices with three alkaline Earth ions in a row

被引:76
作者
Poort, SHM
vanKrevel, JWH
Stomphorst, R
Vink, AP
Blasse, G
机构
[1] Debye Institute, Utrecht University, 3508 TA Utrecht
关键词
D O I
10.1006/jssc.1996.0137
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The luminescence of Eu2+ in Sr-3(PO4)(2):Eu2+, Ba-3(PO4)(2):Eu2+, Ba2Mg(B3O6)(2):Eu2+, and Ba2Ca(B3O6)(2):Eu2+ has been studied. In these structures there are rows of three (large) cations. Emission is observed from Eu2+ on the central and the terminal sites in these rows, the longer wavelength emission originating from Eu2+ on the central site. This assignment is confirmed by measuring the intensity ratios of the emission bands. It fits a model proposed earlier. (C) 1996 Academic Press, Inc.
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页码:432 / 435
页数:4
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