Organic syntheses via transition metal complexes.: 117.: 3-aza-1-metalla-1,3,5-hexatrienes (M = Cr, W):: Generation and π-cyclization to pyrroles

被引：6

作者：

Aumann, R ^{[1
]}

Vogt, D ^{[1
]}

Fröhlich, R ^{[1
]}

机构：

[1] Univ Munster, Organ Chem Inst, D-48149 Munster, Germany

来源：

ORGANOMETALLICS | 2002年 / 21卷 / 09期

关键词：

D O I：

10.1021/om011032d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

3-Aza-1-metallahexa-1,3,5-trienes 3a-f were obtained in good yields by condensation of the (NH2-amino)carbene complexes (CO)(5)M=C(Ph)NH2 (1a,b; M = Cr, W) with alpha,beta-unsaturated acid amides 2 in the presence of phosphoryl chloride and triethylamine. Compounds 3 undergo a thermally induced pi-cyclization to pyrroles 4.

引用

页码：1819 / 1824

页数：6

共 29 条

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